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631.
Sigurdur Jakobsson Jon Blundy Gordon Moore 《Contributions to Mineralogy and Petrology》2014,167(6):1-4
Jakobsson (Contrib Miner Petrol 164(3):397–407, 2012) investigated a double capsule assembly for use in piston-cylinder experiments that would allow hydrous, high-temperature, and high-pressure experiments to be conducted under controlled oxygen fugacity conditions. Using a platinum outer capsule containing a metal oxide oxygen buffer (Ni–NiO or Co–CoO) and H2O, with an inner gold–palladium capsule containing hydrous melt, this study was able to compare the oxygen fugacity imposed by the outer capsule oxygen buffer with an oxygen fugacity estimated by the AuPdFe ternary system calibrated by Barr and Grove (Contrib Miner Petrol 160(5):631–643, 2010). H2O loss or gain, as well as iron loss to the capsule walls and carbon contamination, is often observed in piston-cylinder experiments and often go unexplained. Only a few have attempted to actually quantify various aspects of these changes (Brooker et al. in Am Miner 83(9–10):985–994, 1998; Truckenbrodt and Johannes in Am Miner 84:1333–1335, 1999). It was one of the goals of Jakobsson (Contrib Miner Petrol 164(3):397–407, 2012) to address these issues by using and testing the AuPdFe solution model of Barr and Grove (Contrib Miner Petrol 160(5):631–643, 2010), as well as to constrain the oxygen fugacity of the inner capsule. The oxygen fugacities of the analyzed melts were assumed to be equal to those of the solid Ni–NiO and Co–CoO buffers, which is incorrect since the melts are all undersaturated in H2O and the oxygen fugacities should therefore be lower than that of the buffer by 2 log $a_{{{\text{H}}_{ 2} {\text{O}}}}$ . 相似文献
632.
Jon W. Merritt Maxine C. Akhurst Ian P. Wilkinson James B. Riding Emrys R. Phillips Richard A. Smith Andrew Finlayson Mark T. Dean 《Proceedings of the Geologists' Association. Geologists' Association》2014
An investigation into the late Pleistocene sediments exposed at Afton Lodge has helped to clarify the glacial history of western central Scotland. The sequence includes several allochthonous bodies of ‘shelly clay’ (Afton Lodge Clay Formation) associated with Late Devensian (Weichselian) age diamict. The shelly clay contains abundant marine macro- and microfauna, as well as palynomorphs consistent with its deposition within a shallow marine to estuarine environment. Faunal changes within the main body of marine clay record at least one, millennial-scale cycle of Arctic-Boreal, to Boreal, and back to Arctic-Boreal climatic conditions. A radiocarbon date of over 41 ka 14C BP obtained from the foraminifera indicates that the marine clays are older than the surrounding till. Afton Lodge is thus one of a suite of ‘high-level’ shelly clay occurrences around the Scottish coasts that are now considered to be glacially transported. Together with closely associated ‘shelly tills’, the rafts were emplaced during an early phase of the last glaciation by ice flowing from the western Grampian Highlands of Scotland through the topographically-confined Firth of Clyde basin. The blocks of marine sediment were detached subglacially, unfrozen, and carried at least 10 km by ice that splayed out onshore against reversed slopes favouring raft emplacement and the creation of closely associated ribbed moraine. Transport of the rafts was facilitated by water-lubricated décollement surfaces and their accretion was accompanied by dewatering. The shelly tills were formed mainly by the attenuation and crushing of rafts of shelly clay during their transport within the subglacial deforming bed. 相似文献
633.
Bence Paul Jon D. Woodhead Chad Paton Janet M. Hergt John Hellstrom C. Ashley Norris 《Geostandards and Geoanalytical Research》2014,38(3):253-263
Here, we present an approach to laser ablation ICP‐MS mapping of multi‐phase assemblages that permits the use of different internal standard elements, concentration values and reference materials for each mineral. In this way, we obtain not only broad pictures of elemental distributions within samples but can also extract high accuracy concentration data for any user‐selected region. This is accomplished by assigning regions of an image to corresponding mineral phases on a pixel‐by‐pixel basis. In this way, accurate trace element concentrations can be determined for each mineral phase, despite potential variations in their ablation characteristics. We present an example where elemental maps are constructed from ablation of a gabbroic sample that includes the phases apatite, amphibole and plagioclase. This work represents an important first step towards development of a method to produce highly accurate LA‐ICP‐MS elemental maps of multi‐phase samples. 相似文献
634.
da Silva DA Buzitis J Krahn MM Bícego MC Pires-Vanin AM 《Marine pollution bulletin》2006,52(2):175-183
This study reports the analysis of polycyclic aromatic compound (PAC) metabolites, as biomarkers of exposure to PACs in marine environment. PAC metabolites were measured in bile samples from 14 species of demersal fish caught in the São Sebastião Channel (SSC), SE Brazilian coastline. Naphthalene (NPH) equivalents, phenanthrene (PHN) equivalents, and benzo[a]pyrene (BaP) equivalents were quantified using a reverse-phase high-performance liquid chromatography coupled with fluorescence detection method. For all samples, the means (±standard deviation, n = 37) of concentrations obtained for NPH, PHN, and BaP equivalents were, respectively, 290,000 ± 200,000 ng/g, 18,000 ± 14,000 ng/g, and 970 ± 1900 ng/g. These results indicate recent exposure of these fish to PACs in their environment. In addition, two species (Cyclichthys spinosus and Prionotus nudigula) of fish were analyzed in order to investigate local sources of PAC contamination in the SSC and the influence of the petroleum terminal in fish caught in remote areas. The results showed that these fish species potentially migrate along the channel, especially P. nudigula. Correlations among groups of PAC metabolites indicate the same petrogenic source for NPH and PHN equivalents and a combustion source (e.g., automobile, ships) for BaP equivalents. The ratio BaP/PHN equivalents (0.05 ± 0.07, n = 37) confirms the predominance of petrogenic PACs for contamination by these chemicals in this region. 相似文献
635.
Ulrych Jaromír Krmíček Lukáš Teschner Claudia Řanda Zdeněk Skála Roman Jonášová Šárka Fediuk Ferry Adamovič Jiří Pokorný Richard 《Mineralogy and Petrology》2017,111(5):761-775
Mineralogy and Petrology - Tachylytes from rift-related volcanic rocks were recognized as: (i) irregular veinlets in host alkaline lava flows of the Kozákov volcano, Czech Republic, (ii)... 相似文献
636.
Egli Daniel Mosar Jon Ibele Tobias Madritsch Herfried 《International Journal of Earth Sciences》2017,106(7):2297-2318
International Journal of Earth Sciences - Structural inheritance of preexisting crustal discontinuities is widely accepted to have played a crucial role during the Cenozoic tectonic evolution of... 相似文献
637.
Sr isotope systematics during melt generation by intrusion of basalt into continental crust 总被引:1,自引:1,他引:0
We have studied the Sr isotopic composition of partial melts of biotite granite generated experimentally and by intrusion
of basalt into the Sierra Nevada Batholith. The experiments employed large, 3-cm cubes of granite to duplicate natural grain-boundary
textures and were performed in air over the temperature interval 1000–1250 °C, to simulate basalt-induced wall rock and xenolith
melting in the shallow crust. In both the experimental and natural analogs, fusion of plagioclase + alkali-feldspar ± quartz
and biotite + plagioclase ± quartz results in the formation of colorless and brown melt (quenched to glass) respectively.
Accordant with this melting behavior, brown glasses are enriched in radiogenic Sr and MgO, FeO, CaO, and TiO2 relative to colorless glasses. These results support recent studies indicating that the isotopic compositions of crustal
melts can reflect the relative contributions of mineral phases entering the melt, rather than the isotopic composition of
the bulk source rock. In addition, we show that at shallow-crustal conditions preferential breakdown of biotite leads to initial
high-87Sr/86Sr, low-Sr concentration melts. However, as the degree of melting increases, melts become less radiogenic yet are more enriched
in elemental Sr due to loss of biotite from the restite and increased consumption of feldspars. Our results therefore suggest,
if partial melts of granitic crust segregate rapidly during episodic magmatic underplating, successive melt batches can evolve
from high-87Sr/86Sr to low-87Sr/86Sr liquids as melting progresses.
Received: 25 August 1998 / Accepted: 10 March 1999 相似文献
638.
Jussi Hovikoski Alfred Uchman Rikke Weibel Henrik Nøhr-Hansen Emma Sheldon Jon Ineson Morten Bjerager Jens Therkelsen Mette Olivarius Michael Larsen Peter Alsen Jørgen Bojesen-Koefoed 《Sedimentology》2020,67(7):3619-3654
Reported ancient bottom current deposits in deep marine settings are scarce and most of them remain contentious. This study describes sedimentological, ichnological and petrographical characteristics of a drill core that covers ca 10 Myr of Upper Cretaceous stratigraphy at Hold with Hope, north-east Greenland. The core is divided into four facies associations, which are interpreted to reflect deposition from bottom currents, turbidity flows and hemipelagic settling in slope and/or near slope environments. The evidence for bottom current influence is three-fold. Firstly, pervasive indications of winnowing such as marine bioclast-rich lags and outsized clasts on ‘mud on mud’ contacts are suggestive of low-sediment concentration flows capable of transporting up to pebble-sized clasts. Common Mn–Fe–Mg rich carbonate matrix cements and various types of hiatal chemogenic lag deposits showing glauconite, apatite and carbonate clasts also point to condensation, prolonged exposure at the sediment–water interface and recurrent phases of sea-floor erosion. Secondly, such deposits can show indicators for tidal processes such as double mud-drapes, tangential bottom sets in dune-scale cross-bedding and cyclic rhythmites. Thirdly, inverse to normal grading at various scales is common in fully marine, commonly seafloor-derived sediments. Ichnological data indicate considerable taxonomic variability in the bottom current deposits, but recurrent fabrics are characteristically dominated by morphologically simple burrows such as Thalassinoides and Planolites, with secondary Phycosiphon, Nereites, Zoophycos and/or Chondrites. In general, opportunistic taxa are common whereas mature composite ichnofabrics are rare. The omission surfaces are locally burrowed with stiffground to firmground trace fossil suites. The results contribute to establishing sedimentological, ichnological and mineralogical criteria for recognition of bottom current deposits as well as to the understanding of the Late Cretaceous palaeoenvironmental evolution of the Arctic region. 相似文献
639.
Late Devonian (Famennian) marine successions globally are typified by organic-rich black shales deposited in anoxic and euxinic waters and the cessation of shelf carbonate sedimentation. This global ‘carbonate crisis’, known as the Hangenberg Event, coincides with a major extinction of reef-building metazoans and perturbations to the global carbon cycle, evidenced by positive carbon-isotope excursions of up to 4‰. It has been suggested that authigenic carbonate, formed as cements in sedimentary pore spaces during early burial diagenesis, is a significant mass fraction of the total global carbon burial flux, particularly during periods of low oxygen concentration. Because some authigenic carbonate could have originated from remineralization of organic carbon in sediments, it is possible for this reservoir to be isotopically depleted and thereby drive changes in the carbon isotopic composition of seawater. This study presents bulk isotopic and elemental analyses from fine-grained siliciclastics of the Late Devonian–Early Mississippian Bakken Formation (Williston Basin, USA) to assess the volume and isotopic composition of carbonates in these sediments. Carbonate in the Bakken black shales occurs primarily as microscopic disseminated dolomite rhombs and calcite cements that, together, comprise a significant mass-fraction (ca 9%). The elemental composition of the shales is indicative of a dynamic anoxic to sulphidic palaeoenvironment, likely supported by a fluctuating chemocline. Despite forming in an environment favourable to remineralization of organic matter and the precipitation of isotopically depleted authigenic carbonates, the majority of carbon isotope measurements of disseminated carbonate fall between −3‰ and +3‰, with systematically more depleted carbonates in the deeper-water portions of the basin. Thus, although there is evidence for a significant total mass-fraction of carbonate with contribution from remineralized organic matter, Bakken authigenic carbonates suggest that Famennian black shales are unlikely to be sufficiently 13C-depleted relative to water column dissolved inorganic carbon to serve as a major lever on seawater isotopic composition. 相似文献
640.